王春海的个人主页-西北工业大学教师个人主页

王春海


的个人主页 http://teacher.nwpu.edu.cn/chwang

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基本信息 The basic information

王春海

材料学院

博士研究生毕业

理学博士

副教授

综合介绍 General Introduction

王春海,北京大学理学博士,20189月入职西北工业大学材料学院。分别在山东大学、北京大学获得学士与博士学位,随后在北京大学、中国工程物理研究院、英国杜伦大学、澳大利亚悉尼大学及南方科技大学从事科研工作,主攻固体材料精细晶体结构解析、磁电功能材料的微观机理研究;在陶瓷材料、荧光材料、金属绝缘体相变材料、新型复合阴离子材料、离子导体材料、磁性材料等方面以及第一性原理计算、Raman光谱、红外光谱、精细晶体学结构解析、超短脉冲激光器、X-射线吸收光谱等领域均有创新型的研究成果。参与了澳大利亚基金委员会基金项目、英国工程与科学研究委员会基金项目、国家自然科学基金项目、973国家重大科学研究项目、脉冲中子与同步辐射大型装置实验项目等多项科学研究工作。目前在国际期刊上发表SCI论文总共42篇,其中以第一作者和通讯作者在Chemistry of MaterialsPhysical Review MaterialsInorganic ChemistrJ. Am. Ceram. Soc.等期刊上发表12篇论文,有关磁调制结构及精细结构型变解析的多篇文章被选为美国物理学会、国际晶体学会相关期刊的亮点文章或封面文章,并受邀为多个国际期刊审稿。

ORCID:  0000-0001-5527-199X

ResearcherID: J-2814-2014

 

教育经历 Education Experience

2004.9 – 2009.6 北京大学 化学与分子工程学院    理学博士 专业:无机(固体)化学/材料化学
2000.9 – 2004.7 山东大学 环境科学与工程学院    工学学士 专业:环境工程

学术成果 Academic Achievements

精细晶体结构与磁有序结构解析。基于国际大型国家中子与同步辐射实验装置所获得的高精度衍射数据,通过群论分析与对称性型变(distortion)表象分析法,以体系中的物理作用特征为依据,编写并运用代码控制以TOPAS为内核的高效结构解析方法,成功获得了层状复合阴离子体系Ln2O2MSe2 (Ln = La, Ce; M = Mn, Fe, Cd, Zn)非共度调制晶体结构的精细结构模型,给出了新的Ce2O2MnSe2非共度调制结构模型与低温磁有序结构模型,研究结果发表在材料化学领域顶级期刊Chemistry of Materials上;以此方法也得到了β-Ce2O2FeSe2的低温双调制磁有序结构模型,并在低温m+Sr与Mossbauer谱学测试中得到验证,研究结果发表在Physical Review Materials,被编辑列为该期的亮点文章;基于上述方法研究了磁阻挫材料YCa3(CrO)3(BO3)4与氮氧复合阴离子钙钛矿ATaO2N (A = Ba, Sr)载体的型变结构与相关功能性质,研究结果发表在Inorg. Chem.Acta Cryst. B (封面文章);该结构解析方法具有一定的普适性,可为功能材料的研究与理论模拟提供关键的精细晶体结构信息;

基于粉末衍射技术的非共度调制结构解析方法。针对非共度调制结构的复杂调制矢量q需要高品质的单晶衍射数据这一技术难题,发展了一套基于粉末衍射数据的材料非共度调制结构解析方法,并成功用于对高温氧缺陷非整比AUO4-x (A = Ca, Sr)的非共度调制结构的解析工作;

材料局域结构的研究。综合理论模拟方法与同步辐射技术研究了高效荧光粉Ca5(PO4)3Cl:Eu2+中发光中心离子Eu2+的化学环境与局域结构及其与发光行为之间的关系,给出其优势占位与局域结构变形特征,对发光材料的设计与开发具有重要指导意义,相关工作发表在J. Solid State Chem.

无机固体材料的声子行为研究。利用第一性原理计算方法结合精密的实验测量,分析了MgTiO3、复合钙钛矿Ba(Mg1/3Ta2/3)O3、Ba(Mg1/2W1/2)O3陶瓷中晶格动力学行为,给出Raman与红外声子的精细谱学指认,并研究了相关声子对晶格有序度与高频介电行为的响应与影响,相关方法可用于Raman、红外、非弹性中子散射技术对其他功能材料的研究,相关工作发表在J. Appl. Phys.J. Am. Ceram. Soc.等期刊 


发表论文情况:

42.  D.-Y. Gui, Z.-K. Cao, W. Han, J.-Q. Qi, T.-C. Lu, Y. Zou, C.-H. Wang*, “Effects of cation ordering and microstructure on LaGdZr2O7 transparent ceramics processing by vacuum sintering”, Ceram. Int. 44, 7006-7012 (2018). 

41.  C.-H. Wang, C. M. Ainsworth, S. D. Champion, G. A. Stewart, M. C. Worsdale, T. Lancaster, S. J. Blundell, Helen E. A. Brand, and John S. O. Evans, “Crystal structure and magnetic modulation in β-Ce2O2FeSe2”, Phys. Rev. Mater. 1, 034403 (2017) (Editor Highlight).

40.  C.-H. Wang, B. J. Kennedy, A. L. Menezes de Oliveira, J. Polt and K. S. Knight, “The impact of anion ordering on octahedra distortion and phase transitions in SrTaO2N and BaTaO2N”, Acta Cryst. B73, 389-398 (2017) (Cover). 

39.  C.-H. Wang, M. Avdeev, B. J. Kennedy, M. Ku?pers, and C. D. Ling “YCa3(CrO)3(BO3)4: A Cr3+ Kagome? Lattice Compound Showing No Magnetic Order down to 2 K” Inorg. Chem., 55, 7535-7541 (2016). 

38.  C.-H. Wang, C. M. Ainsworth, D.-Y. Gui, E. E. McCabe, M. G. Tucker, I. R. Evans and J. S. O. Evans “Infinitely adaptive transition metal oxychalcogenides: the modulated structures of Ce2O2MnSe2 and (Ce0.78La0.22)2O2MnSe2Chem. Mater. 27, 3121-3134 (2015). 

37.  C.-H. Wang*, D.-Y. Gui, R. Qin, F.-L. Yang, X.-P. Jing, G.-S. Tian, and W. Zhu “Site and local structure of activator Eu2+ in phosphor Ca10-x(PO4)6Cl2:xEu2+”, J. Solid State Chem., 206, 69-74 (2013). 

36.  C.-H. Wang#, C.-L. Diao, N.-N. Luo, Z.-M. Qi, T. Shao et al., “First-Principle Calculation and Assignment for Vibrational Spectra of Ba(Mg1/2W1/2)O3 Microwave Dielectric Ceramic”, J. Am. Ceram. Soc., 96[9], 2898-2905 (2013).

35.  C.-H. Wang*, D.-F. Guo, Z. Li, X.-M. Wang, J.-H. Lin, Z. Zeng, and X.-P. Jing, “Crystal structure of Sr6Y2Al4O15: XRD refinements and first-principle calculations”, J. Solid State Chem., 192, 195-200 (2012). 

34.  C.-H. Wang, G.-H. Liu, X.-P. Jing, G.-S. Tian, X. Lü and J. Shao, “First-principle calculation and far infrared measurement for infrared-active modes of Ba(Mg1/3Ta2/3)O3”, J. Am. Ceram. Soc., 93[11], 3782-3787 (2010).

33.  C.-H. Wang, X.-P. Jing, L. Wang and J. Lu, “XRD and Raman studies on the ordering/disordering of Ba(Mg1/3Ta2/3)O3”, J. Am. Ceram. Soc., 92[7], 1547-1551 (2009). 

32.  C.-H. Wang, X.-J. Kuang, X.-P. Jing, J. Lu, X. Lü and J. Shao, “Far infrared reflection spectra and IR active modes of MgTiO3”, J. Appl. Phys., 103[7], 074105 (2008). 

31.  C.-H. Wang, X.-P. Jing, W. Feng and J. Lu, “Assignment of the Raman active vibrational modes of MgTiO3”, J. Appl. Phys., 104[3], 034112 (2008). 

30.  G. L. Murphy, C.-H. Wang, G. Beridze, Z. Zhang, J. A. Kimpton, M. Avdeev, P. M. Kowalski, B. J. Kennedy, “Unexpected Crystallographic Phase Transformation in Nonstoichiometric SrUO4-x: Reversible Oxygen Defect Ordering and Symmetry Lowering with Increasing Temperature”, Inorg. Chem., 57, 5948-5958 (2018).

29.  D.-Y. Gui*, C.-H. Wang, W. Zhu, C. Meng, “Phase controlled Raman modes and dielectric properties in (1-x)MgTiO3-x(Mg4Ta2O9)1/3”, J. Alloy. Compd. 730, 434-440 (2018).

28.  H.-W. Wei, X.-M. Wang, X.-J. Kuang, C.-H. Wang, H. Jiao and X.-P. Jing, “The structure, anion order, and Ce3+ luminescence of Y4Al2O9-Y4Si2O7N2 solid solutions”, J. Mater. Chem. C, 5, 4654-4660 (2017).

27.  C. M. Ainsworth, J. W. Lewis, C.-H. Wang, H. E. Johnstone, B. G. Mendhis, H. E. A. Brand, A. A. Coelho, J. S. O. Evans “3D Transition Metal Stacking Control in La2O2Cu2-4xCd2xSe2Chem. Mater. 28, 3184-3195 (2016).

26.  C. M. Ainsworth, C.-H. Wang, M. G. Tucker, and J. S. O. Evans “Infinitely Adaptive Transition-Metal Ordering in Ln2O2MSe2Type Oxychalcogenides” Inorg. Chem. 54, 7230-7238 (2015). (Cover)

25.  AN Wei, LIU Tianhui, WANG Chunhai et al. “Assignment for Vibrational Spectra of BaTiO3 Ferroelectric Ceramic Based on the First-Principles Calculation” Acta Phys. -Chim. Sin., 31, 1059-1068 (2015). (Cover)

24.  X. Zhang, X.-M. Wang, H.-W. Wei, X.-H. Lin, C.-H. Wang, Y. Zhang, C. Chen, X.-P. Jing, “Effect of oxygen content on transport and magnetic properties of PrBaCo2O5.50+δ”, Mater. Res. Bull., 65 80-88 (2015).

23.  C. M. Ainsworth, C.-H. Wang, M. G. Tucker, J. S. O. Evans, “Synthesis, Structural Characterization and Physical Properties of the New Transition Metal Oxyselenide Ce2O2ZnSe2Inorg. Chem., 54, 1563-1571 (2015).

22.  A. J. Tuxworth, C.-H. Wang, and J. S. O. Evans, “Synthesis, Characterisation and Properties of Rare Earth Oxyselenides A4O4Se3 (A = Eu, Gd, Tb, Dy, Ho, Er, Yb and Y)” Dalton Trans., 44, 3009-3019 (2015).

21.  S. E. Nunes, C.-H. Wang, K. So, J. S. O. Evans and I. R. Evans, “Bismuth Zinc Vanadate, BiZn2VO6: New Crystal Structure Type and Electronic Structure”, J. Solid State Chem., 222, 12-17 (2015).

20.  Y.-J. Li, S. Ye, C.-H. Wang, X.-M. Wang and Q.-Y. Zhang, “Temperature-dependent near-infrared emission of highly concentrated Cu2+ in CaCuSi4O10 phosphor”, J. Mater. Chem. C, 2, 10395 (2014).

19.  C.-L. Diao, C.-H. Wang, N.-N. Luo, Z.-M. Qi, T. Shao et al., “First-principle calculation and assignment for vibrational spectra of Ba(Mg1/3Nb2/3)O3 microwave dielectric ceramic”, J. Appl. Phys., 115[11], 114103 (2014).

18.  X. Zhang, X.-J. Kuang, Y.-G. Wang, X.-M. Wang, C.-H. Wang, Y. Zhang, C. Chen, and X.-P. Jing, “Transport and Magnetic Properties of MgFeVO4Jpn. J. Appl. Phys., 52[3], 023001 (2013).

17.  R. Wang, C. Yang, M. Fan, M. Wu, C. Wang, X. Yu et al., “Phase relationship of the TbO1.81-Mn3O4-Fe2O3 system synthesized at 1200 °C” J. Alloys Compd., 554, 385-394 (2013).

16.  X. Li, L. Xu, X. Cao, C. Meng, C. Wang, and W. Zhu, “Synthesis of CsCl-type single-phase RuSi under shock compression” High Pressure Res., 33[1], 8-14 (2013).

15.  R. Qin, C.-H. Wang, W. Zhu, and Y. Zhang,” First-principles calculations of mechanical and electronic properties of silicene under strain”, AIP Advances, 2, 022159 (2012).

14.  X.-M. Wang, C.-H. Wang, X.-J. Kuang, R.-Q. Zou, Y.-X. Wang, and X.-P. Jing, “Promising Oxonitridosilicate Phosphor Host Sr3Si2O4N2: Synthesis, Structure, and Luminescence Properties Activated by Eu2+ and Ce3+/Li+ for pc-LEDs”, Inorg. Chem., 51[6], 3540-3547 (2012).

13.  X.-M. Wang, C.-H. Wang, M.-M. Wu, Y.-X. Wang and X.-P. Jing, “O/N ordering in the structure of Ca3Si2O4N2 and the luminescence properties of the Ce3+ doped material”, J. Mater. Chem., 22[8], 3388–3394 (2012).

12.  G.-H. Liu, and C.-H. Wang “Existence of Bond-Order-Wave Phase in One-Dimensional Extended Hubbard Model”, Commun. Theor. Phys. 55[4] 702-708 (2011).

11.   G.-H. Liu, C.-H. Wang and X.-Y. Deng, “Quantum entanglement and quantum phase transitions in frustrated Majumdar–Ghosh model”, Physica B, 406[1], 100 (2011).

10.  G.-H. Liu, X.-Y. Deng and C.-H. Wang, “Theoretical study of metal-insulator transition in rhombohedral vanadium sesquioxide”, J. Phys. Chem. Solids, 72[9], 1085-1089 (2011).

9.     G.-H. Liu, X.-Y. Deng and C.-H. Wang, “Electronic and Optical Properties of Monoclinic and Rhombohedral Vanadium Sesquioxide”, Chinese J. Struc. Chem., 30[5], 638-643 (2011).

8.     H. Zhu, X.-J. Kuang C.-H. Wang, H.-T. Xia, L. Li, P. Hu, X.-P. Jing, Z. X. Tang, F. Zhao and Z.-X. Yue, “Annealing Effects on Conductivity and Microwave Dielectric Loss of MgTiO3 Ceramics”, Jpn. J. Appl. Phys.-Part 1, 50[6], 065806 (2011).

7.     H.-T. Xia, X.-J. Kuang C.-H. Wang, W.-X. Li, X.-P. Jing, F. Zhao and Z.-X. Yue, “Conductivity and Dielectric Loss of Tungsten-Bronze-Type BaNd2Ti4O12 Microwave Ceramics”, Acta Physico-Chimina Sinica, 27[8], 2009-2014 (2011).

6.     P. Hu, H. Jiao, C.-H. Wang, X.-M. Wang, S. Ye, X.-P. Jing, F. Zhao and Z.-X. Yue, “Influence of thermal treatments on the low frequency conductivity and microwave dielectric loss of CaTiO3 ceramics” Mater. Sci. Eng. B, 176[5], 401-405 (2011).

5.     H. Wang, C.-H. Wang, G.-B. Li, T.-N. Jin, F.-H. Liao and J.-H. Lin, “Synthesis, Structure, and Characterization of the Series BaBi1-xTaxO3 (0 <= x <= 0.5)”, Inorg. Chem., 49[11], 5262-5270 (2010).

4.     S. Ye, C.-H. Wang and X.-P. Jing, “Long Wavelength Extension of the Excitation Band of LiEuMo2O8 Phosphor with Bi3+ Doping”, J. Electrochem. Soc., 156[6], J121-J124 (2009).

3.     S. Ye, C.-H. Wang, Z.-S. Liu and X.-P. Jing, “Photoluminescence and Raman spectra of double-perovskite Sr2Ca(Mo/W)O6 with A- and B-site substitutions of Eu3+”, J. Electrochem. Soc. 155[6], J148-J151 (2008).

2.     S. Ye, C.-H. Wang, Z.-S. Liu and X.-P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications”, Appl. Phys. B91, 551-557 (2008).

        1.      X.-J. Kuang, H.-T. Xia, F.-H. Liao, C.-H. Wang, L. Li and X.-P. Jing, “Doping Effects of Ta on Conductivity and Microwave Dielectric Loss of MgTiO3 Ceramics”, J. Am. Ceram. Soc., 90[10], 3142 (2007).



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