张秋禹


的个人主页 http://teacher.nwpu.edu.cn/zhangqiuyu

基本信息 The basic information

张秋禹

理学院

博士研究生毕业

博士

教授

副院长

材料科学与工程

qyzhang@nwpu.edu.cn;或qyzhang1803@gmail.com

029-88431653

工作经历 Work Experience

1990-2000年,西北工业化工系任讲师、副教授

2000-2002年,西北工业大学化工系教授

2002-2004年,在Loughborough大学和英国皇家学会的资助下,在英国从事了近两年的科学研究工作,主要从事利用反相微乳液聚合技术制备高分子高分子/无机氧化物纳米复合材料的研究工作。 

2004-至今,西北工业大学理学院教授

2009-至今,西北工业大学理学院教授,长江学者特聘教授

教育经历 Education Experience

 1983.08-1987.07,北京化工学院本科攻读学士学位,分析化学

1987.09-1990.04,科学院北京化学所硕士攻读硕士学位,结构化学

1995.09-1999.09,西北工业大学材料学院攻读博士学位,材料学 

教育教学 Education And Teaching

研究方向

  应用聚合物表界面化学
  微纳米多孔高分子

  高性能高分子与杂化复合材料的设计合成与应用

  智能响应性高分子

  新型能源材料的结构设计与合成

 
教学状况

  主讲博士研究生《超分子化学》课程

  主讲博士研究生《高分子近代合成方法》课程

  主讲硕士研究生《有机合成原理》课程 

招生信息 Admission Information

研究生招生

(1)化学一级学科博士

(2)材料学学科博士

上述相关学科硕士以及应用化学和化学工艺学科硕士

欢迎有志于与本研究方向有关的青年学子加入课题组或从事博士后研究! 

荣誉获奖 Awards Information

曾获省部级奖6项,主要有

陕西省科技奖一等奖,2007年。

陕西省科技奖 二等奖,2008年。

陕西省科技奖 二等奖, 2015年

获陕西省青年科技奖、教育部霍英东青年教师奖、国务院政府特殊津贴、巾帼建功立业标兵等荣誉

学术成果 Academic Achievements

作为课题负责人先后承担国家自然科学基金重点项目、面上项目、973前期课题、863重大专项课题、国防基础科研、国防技术基础、多项军品型号配套项目、陕西省自然基金、陕西省科技计划项目、航空基金、航天基金等多项课题的研究。先后获陕西省科技奖一等奖1项,二等奖2项等多项科研奖,发表科研论文300余篇。获授权发明专利40余项。并获陕西省青年科技奖,教育部霍英东优秀青年教师奖等多项奖励。

3年主持的主要科研项目

国家自然基金重点项目:蛋白印迹响应性高分子磁性复合微球多层次结构调控与性51433008

国家自然基金面上项目:多点接枝协同可逆共价交联结构聚合物弹性体合成与性能研究51673156

国家自然基金面上项目:新型磁性多层次组装单元构建及磁场下组装响应机制研究 51173146

国家863项目:腮腺炎减毒活疫苗等病毒性疫苗关键技术及产品研发 2012AA02A404

国家重点基础研究发展计划:微纳米高分子复合颗粒材料合成与应用基础研究2010CB635111

深圳市科技计划项目,海洋航行器超疏水表面减阻技术研发,JCYJ20160331142330969 

其中代表性学术论文如下:

1. A series of nanoparticles with phase-separated structures by 1,1-diphenylethene controlled one-step soap-free emulsion copolymerization and their application in drug release[J]. Nano Research, 2017, 10(9):2905-2922.
2. Morphology-dependent electrochemical supercapacitors in multi-dimensional polyaniline nanostructures[J]. Journal of Materials Chemistry A, 2017, 5, 5, 14041-14052.
3. Fabrication of hollow mesoporous SiO 2-BiOCl@ PANI@ Pd photocatalysts to improve the photocatalytic performance under visible light, Applied Catalysis B: Environmental, 2017, 213: 136-146.
4. Large-scale fabrication of polymer ellipsoids with controllable patches via the viscosity-induced deformation of spherical particles[J]. Polymer Chemistry, 2017, 8, 3774-3777
5. Preparation of Mechanoresponsive Hairy Particles Using Polymeric Surfactants in Emulsion Polymerization, Polymer Chemistry, 2017,8, 3971-3976.

6. Microencapsulation through thermally sintering Pickering emulsion-based colloidosomes, Soft Matter, 2017, 13, 3720-3725.

7. Cetyl trimethyl ammonium bromide (CTAB) micellar templates directed synthesis of water-dispersible polyaniline rhombic plates with excellent processability and flow-induced color variation, Polymer, 2017(117) 30-36.

8. Synergistic improvement of thermal conductivities of polyphenylene sulfide composites filled with boron nitride hybrid fillers, Composites Part A: Applied Science and Manufacturing, 2017(95) 267-273.

9. Facile synthesis of imidazole microcapsules via thiol-click chemistry and their application as thermally latent curing agent for epoxy resins, Composites Science and Technology, 2017(142) 198-206.

10. Fabrication of Liquid Protrusions on Non-Cross-Linked Colloidal Particles for Shape-Controlled Patchy Microparticles. Macromolecules 2016, 49, 9626-9636.

11. Preparation of lipase/Zn3(PO4)2, hybrid nanoflower and its catalytic performance as an immobilized enzyme[J]. Chemical Engineering Journal, 2016, 291:287-297. (IF:5.310)

12. Synthesis of BiOBr/carbon quantum dots microspheres with enhanced photoactivity and photostability under visible light irradiation[J]. Applied Catalysis A General, 2016, 527:127-136.(IF:4.012)

13. Highly thermally conductive flame-retardant epoxy nanocomposites with reduced ignitability and excellent electrical conductivities[J]. Composites Science and Technology, 2017, 139: 83-89.(IF=3.897)

14. Dielectric thermally conductive boron nitride/polyimide composites with outstanding thermal stabilities via in-situ polymerization-electrospinning-hot press method. Composites Part A: Applied Science and Manufacturing, 2017, 94: 209-216. (IF=3.791)

15. Preparation of lipase/Zn3(PO4)2, hybrid nanoflower and its catalytic performance as an immobilized enzyme[J]. Chemical Engineering Journal, 2016, 291:287-297. (IF:5.310)

16. Synthesis of BiOBr/carbon quantum dots microspheres with enhanced photoactivity and photostability under visible light irradiation[J]. Applied Catalysis A General, 2016, 527:127-136.(IF:4.012) ?

17. ChemInform Abstract: Metallocenium Chemistry and Its Emerging Impact on Synthetic Macromolecular Chemistry[J]. ChemInform, 2016, 47(25):no-no.(IF:3.949)

18. Highly thermally conductive flame-retardant epoxy nanocomposites with reduced ignitability and excellent electrical conductivities[J]. Composites Science and Technology, 2017, 139: 83-89.(IF=3.897)

19. Dielectric thermally conductive boron nitride/polyimide composites with outstanding thermal stabilities via in-situ polymerization-electrospinning-hot press method. Composites Part A: Applied Science and Manufacturing, 2017, 94: 209-216. (IF=3.791)

20. Deformation behavior of oriented β-crystals in injection-molded isotactic polypropylene by in situ X-ray scattering[J]. Polymer, 2016, 84: 254-266.(IF:3.586)

21. Fabrication of modified bismaleimide resins by hyperbrnched phenyl polysiloxane and their improvement of thermal conductivities[J]. Rsc Advances, 2016, 6(62). (IF:3.289)

22. Red-blood-cell-like BSA/Zn3(PO4)2, hybrid particles: Preparation and application to adsorption of heavy metal ions[J]. Applied Surface Science, 2016, 366(3):328-338.(IF:3.150)

23. Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity[J]. International Journal of Heat & Mass Transfer, 2016, 92:15-22. (IF=2.857)

24. Antagonistic effect of particles and surfactant on pore structure of macroporous materials based on high internal phase emulsion[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2016, 506:550-556.(IF:2.760)

25. Fabrication and Properties of Thermally Conductive Epoxy Resin Nanocomposites Filled with fGNPs/PNBRs Hybrid Fillers[J]. Science of Advanced Materials, 2016, 8(5):972-979.(IF=1.8)

26. Toughness Reinforcement in Carbon Nanotube-Filled High Impact Polypropylene Copolymer with β-Nucleating Agent[J]. Industrial & Engineering Chemistry Research, 2016, 55(32): 8733-8742.(IF:2.567)

27. Promoting Mechanochemistry of Covalent Bonds by Noncovalent Micellar Aggregation[J]. ACS Macro Letters, 2016, 5(9): 995-998.(IF:5.766)

28. Impressed Pressure-Facilitated Seeded Emulsion Polymerization: Design the Fast Swelling Strategies for Massive Fabrication of Patchy Microparticles[J]. Polymer Chemistry, 2016, 7, 7078-7085. (IF:5.687)

29. Fabrication of Liquid Protrusions on Non-Cross-Linked Colloidal Particles for Shape-Controlled Patchy Microparticles[J]. Macromolecules, 2016, 49, 9626–9636.(IF:5.554)

30. One-step thiol-isocyanate dispersion polymerization: preparation of uniform, cross-linked and functional particles[J]. Chemical Engineering Journal, 2016, 304:461-468. (IF:5.310)

31. Dependency of tunable microwave absorption performance on morphology-controlled hierarchical shells for core-shell Fe3O4@MnO2, composite microspheres[J]. Chemical Engineering Journal, 2016, 304:552-562. (IF:5.310)

32. Synthesis of magnetically separable Fe 3 O 4 @PANI/TiO 2, photocatalyst with fast charge migration for photodegradation of EDTA under visible-light irradiation[J]. Chemical Engineering Journal, 2016, 303:282-291. (IF:5.310)

33. Effect of the Structure and Length of Flexible Chains on Dendrimers Grafted Fe3O4@SiO2/PAMAM Magnetic Nanocarriers for Lipase Immobilization [J].ACS Sustainable Chemistry & Engineering. 2016, 4, 6382–6390.(IF:5.267)

34. Amino-Fe3O4 Microspheres Directed Synthesis of a Series of Polyaniline Hierarchical Nanostructures with Different Wettability[J]. Scientific Reports, 2016, 6, 33313-33321.(IF:5.228)

35. Hyperbranched polysiloxane (HBPSi)-based polyimide films with ultralow dielectric permittivity, desirable mechanical and thermal properties[J]. Journal of Materials Chemistry C, 2016, 4(11):2134-2146. (IF:5.066)

36. Preparation of anti-nonspecific adsorption polydopamine-based surface protein-imprinted magnetic microspheres with the assistance of 2-methacryloyloxyethyl phosphorylcholine and its application for protein recognition[J]. Sensors & Actuators B Chemical, 2017, 241:413-421.(IF:4.758)

37. Design of Raspberry‐Shaped Microcarriers with Adjustable Protrusions and Functional Groups for the Improvement of Lipase Immobilization and Biocatalysis: Environmentally Friendly Esterification of Oleic Acid for Biodiesel (ChemCatChem 16/2[J]. ChemCatChem, 2016, 8(16):2574-2574.(IF:4.724)

38. Tunable Permittivity in High–Performance Hyperbranched Polyimide Films by Adjusting Backbone Rigidity[J]. Journal of Physical Chemistry C, 2016, 120(5), 2548–2561.(IF:4.509)

39. Novel BiOCl/TiO 2, hierarchical composites: Synthesis, characterization and application on photocatalysis[J]. Applied Catalysis A General, 2016, 516:81-89. (IF:4.012)

40. Rapid and efficient synthesis of isocyanate microcapsules via thiol-ene photopolymerization in Pickering emulsion and its application in self-healing coating[J]. Composites Science & Technology, 2016, 123(4):250-258.(IF:3.897)

41. Robust, self-healing, superhydrophobic coatings highlighted by a novel branched thiol-ene fluorinated siloxane nanocomposites[J]. Composites Science & Technology, 2016, 137:78-86. (IF:3.897)

42. Preparation of Light Core/Shell Magnetic Composite Microspheres and Its Application to Lipase Immobilization[J]. Rsc Advances, 2016, 6(70), 65911-65920. (IF:3.289)

43. “Ultrahigh humidity sensitivity of NaCl-added 3D mesoporous silica KIT-6 and its sensing mechanism” RSC Advances, 2016, 6, 38391-38398. (IF:3.289)

44. Preparation of One-dimensional Fe3O4@P(MAA-DVB)-Pd(0) Magnetic Nanochains and Its application for rapid degradation of Organic Dyes[J]. Rsc Advances, 2016. (IF:3.289)

45. Facile synthesis of LiCo1/3Ni1/3Mn1/3O2/Al(OH)3 composite as a high-performance cathode material for lithium ion cells[J]. Journal of Alloys & Compounds, 2016, 656:849-853.(IF:3.014)

46. Facile synthesis and enhanced electromagnetic microwave absorption performance for porous core-shell Fe3O4 @MnO2, composite microspheres with lightweight feature[J]. Journal of Alloys & Compounds, 2016, 693:432-439. (IF:3.014)

47. Fabrication and Characterization of Electrospun Dopants/PS Composite Fibers with Porous and Hollow Porous Structures[J]. Macromolecular Materials & Engineering, 2016, 301(5):625-635. (IF:2.834)

48. Preparation of quaternary amine monolithic column for strong anion-exchange chromatography and its application to the separation of Enterovirus 71.[J]. Journal of Chromatography B, 2016, 1033-1034:399-405.(IF:2.687)

49. Well-Defined Core-Shell Fe3O4@Polypyrrole Composite Microspheres with Tunable Shell Thickness: Synthesis and Their Superior Microwave Absorption Performance in the Ku Band[J]. Industrial & Engineering Chemistry Research, 2016, 55(22).(IF:2.567)

50. Multidimensional polyaniline structures from micellar templates[J]. Journal of Materials Science, 2016, 1-8.(IF:2.302)

51. Hypercrosslinked polymers: controlled preparation and effective adsorption of aniline[J]. Journal of Materials Science, 2016, 51(18):8579-8592. (IF:2.302)

52. Immobilization of lipase on mesoporous silica nanoparticles with hierarchical fibrous pore[J]. Journal of Molecular Catalysis B: Enzymatic, 2016, 134: 129-135.(IF:2.189)

53. Synthesis of magnetically separable core–shell structured NixFe1?x Fe2O4@TiO2, nanoparticles photocatalysts for the degradation of organic dyes[J]. Journal of Porous Materials, 2016:1-8.(IF:1.385)

54. Grafting–through Strategy in Emulsion: An Eco–friendly and Effective Route for the Synthesis of Graft Copolymers[J]. ChemistrySelect, 2016, 1(9):1870-1878.

55. Magnetic microcapsules with inner asymmetric structure: Controlled preparation, mechanism, and application to drug release. Chemical Engineering Journal, 2015. 275: 235-244.

56. Generalized approach for fabricating monodisperse anisotropic microparticles via single-hole swelling PGMA seed particles. Macromolecules, 2015. 48(20): 7592-7603.

57. Water-borne thiol-isocyanate click chemistry in microfluidics: rapid and energy-efficient preparation of uniform particles. Polymer Chemistry, 2015, 6, 4366–4373.

58. Thiol–isocyanate click reaction in a Pickering emulsion: a rapid and efficient route to encapsulation of healing agents. Polymer Chemistry, 2015. 6(40): 7100-7111.

59. Large-Scale fabrication of polymer microcavities with adjustable openings and surface roughness regulated by the polarity of both seed surface and monomers. Macromolecular rapid communications, 2015 DOI: 10.1002/marc.201500449.

60. Hollow mesoporous SiO2-BiOBr nanophotocatalyst: Synthesis, characterization and application in photodegradation of organic dyes under visible-light irradiation. ACS Sustainable Chemistry & Engineering, 2015,3,1101-1110.

61. Fabricating and tailoring polyaniline (PANI) nanofibers with high aspect ratio in a low-acid environment in a magnetic field. Chemistry–An Asian Journal, 2015. DOI:10.1002/asia.201500826.

62. Efficient photocatalytic degradation of dyes over hierarchical BiOBr/β-Co(OH)2/PVP multicomponent photocatalyst under visible-light irradiation. ChemCatChem, 2015,7,4163-4172.

63. Evolution of surface chemistry and morphology of hyperbranched polysiloxane polyimides in simulated atomic oxygen environment. Corrosion Science, 2015. 98: 560-572.

64. Fabrication of electromagnetic Fe3O4@ polyaniline nanofibers with high aspect ratio. RSC Advances, 2015. 5(13): 9986-9992.

65. Fast magnetic-field-induced formation of one-dimensional structured chain-like materials via sintering of Fe3O4/poly(styrene-co-n-butyl acrylate-co-acrylic acid) hybrid microspheres. RSC Advances, 2015. 5(36): 28735-28742.

66. Synthesis of CdTe/P(St-nBA-AA) pierced fluorescent microspheres. RSC Advances, 2015. 5(42): 33554-33561

67. Synthesis of rattle-type magnetic mesoporous Fe3O4@mSiO2@BiOBr hierarchical photocatalyst and investigation of its photoactivity in the degradation of methylene blue. RSC Advances, 2015. 5(59): 48050-48059.

68. Quaternary ammonium functionalized Fe3O4@P(GMA–EGDMA) composite particles as highly efficient and dispersible catalysts for phase transfer reactions. RSC Advances, 2015. 5(75): 60691-60697.

69. Micron-sized flower-like Fe3O4@GMA magnetic porous microspheres for lipase immobilization. RSC Advances, 2015. 5(112): 92449-92455.

70. Regulating the size and molecular weight of polymeric particles by 1, 1-diphenylethene

71. Novel Janus magnetic micro particle synthesis and its applications as a demulsifier for breaking heavy crude oil and water emulsion[J]. Fuel, 2015, 141: 258–267.

72. Effect of carboxyl density at the core–shell interface of surface-imprinted magnetic trilayer microspheres on recognition properties of proteins[J]. Sensors and Actuators B: Chemical, 2014, 196:265-271.

73. Preparation and characterization of bovine serum albumin surface-imprinted thermosensitive magnetic polymer microsphere and its application for protein recognition[J]. Biosensors and Bioelectronics, 2014, 51:261-267.

74. One-pot hydrothermal synthesis of highly monodisperse water-dispersible hollow magnetic microspheres and construction of photonic crystals[J]. Chemical Engineering Journal, 2015, 259:779-786.

75. Fast and facile fabrication of porous polymer particles via thiol–ene suspension photopolymerization[J]. Rsc Advances, 2014, 4:13334-13339.

76. Facile fabrication of Fe3O4@ PS/PGMA magnetic Janus particles via organic-inorganic dual phase separation[J]. Rsc Advances, 2014, 4, 27152-27158.

77. Synthesis and Characterization of Comb and Centipede Multigraft Copolymers P n BA-g-PS with High Molecular Weight Using Miniemulsion Polymerization[J]. Macromolecules, 2014, 47, 7284-7295.

78. Fabrication of highly dispersed ZnO nanoparticles embedded in graphene nanosheets for high performance supercapacitors[J]. Electrochimica Acta, 2014, 148:164-169.

79. Colloidal particles with various glass transition temperatures: preparation, assembly, and the properties of stop bands under heat treatment[J]. Journal of Materials Science, 2014, 49:2653-2661

80. Pickering emulsion: A novel template for microencapsulated phase change materials with polymer–silica hybrid shell[J]. Energy, 2014, 64:575-581.

81. Improved space survivability of polyhedral oligomeric silsesquioxane (POSS) polyimides fabricated via novel POSS–diamine[J]. Corrosion Science, 2014, doi:10.1016/j.corsci.2014.10.013.

82. Synthesis and gas permeation properties of hyperbranched polyimides membranes from novel(A2+ B2B′+B2)-type method. Journal of Membrane Science,2014,450: 138-146.

83. Space Survivable Polyimides with Excellent Optical Transparency and Self-Healing Properties Derived from Hyperbranched Polysiloxane, ACS Appl. Mater. Interfaces, 2013,5:10207–10220

84. Synthesis of Raspberry-Like Poly(styrene–glycidyl methacrylate) Particles via a One-Step Soap-Free Emulsion Polymerization Process Accompanied by Phase Separation. Langmuir. 2013,29: 11730-11741.

85. Preparation and characterization of novel immobilized Fe3O4@SiO2@mSiO2–Pd(0) catalyst with large pore-size mesoporous for Suzuki coupling reaction. Applied Catalysis A: General. 2013,459: 65-72.

86. Synthesis of poly (methyl methacrylate)-b-polystyrene with high molecular weight by DPE seeded emulsion polymerization and its application in proton exchange membrane. Journal of Colloid and Interface Science. 2013,406: 154-164.

87. Preparation of thermoresponsive Fe3O4/P(acrylic acid–methyl methacrylate–N-isopropylacrylamide) magnetic composite microspheres with controlled shell thickness and its releasing property for phenolphthalein. Journal of Colloid and Interface Science. 2013,398: 51-58.

88. One-Pot Synthesis of Highly Magnetically Sensitive Nanochains Coated with a Fluorescent Shell by Magnetic-Field-Induced Precipitation Polymerization. Science of Advanced Materials. 2013,5: 623-629.

89. Synthesis of BSA/Fe3O4magnetic composite microspheres for adsorption of antibiotics. Materials Science and Engineering: C.2013,33: 4401-4408.

90. Preparation and characterization of structure-tailored magnetic fluorescent Fe3O4/P(GMA–EGDMA–NVCz) core–shell microspheres. Journal of Materials Science.2013,48: 5302-5308.

91. Encapsulation and dispersion of carbon black by an in situ controlling radical polymerization of AA/BA/St with DPE as a control agent, Colloid and Polymer Science, 2013,291: 2399-2408.

92. Three new conjugated polymers based on benzo[2,1-b:3,4-b ']dithiophene: synthesis, characterization, photoinduced charge transfer and theoretical calculation studies, Polymer Chemistry .2012,3: 2244-2253.

93. Fabrication of one-dimensional Fe3O4/P(GMA-DVB) nanochains by magnetic-field-induced precipitation polymerization. Journal of Colloid and Interface Science.2012,374: 339-344.

94. Synthesis of block copolymer poly (n-butyl acrylate)-b-polystyrene by dpe seeded emulsion polymerization with monodisperse latex particles and morphology of self-assEMBLY film surface. Journal of Colloid and Interface Science.2012,374: 54-60.

95. Humidity sensing mechanism of mesoporous MgO/KCl–SiO2 composites analyzed by complex impedance spectra and bode diagrams”. Sensors and Actuators B 174 (2012) 513– 520

96. Fabrication of 1D Fe3O4/P(NIPAM-MBA) thermosensitive nanochains by magnetic-field-induced precipitation polymerization. Colloid and Polymer Science.2012,290: 1207-1213.

97. Synthesis of block copolymer poly (n-butyl acrylate)-b-polystyrene by DPE seeded emulsion polymerization with monodisperse latex particles and morphology of self-assembly film surface, Journal of colloid and interface science, 2012, 374: 54-60

98. Preparation of high-magnetization Fe3O4–NH2–Pd (0) catalyst for Heck reaction. Catalysis communications, 2012, 17: 168-172

99. Supported nanosized palladium on superparamagnetic composite microspheres as an efficient catalyst for Heck reaction. Catalysis communications, 2010,11:606-610

100.Fabrication of 1D Fe3O4/P(NIPAM-MBA) thermosensitive nanochains by magnetic-field-induced precipit ation polymerization. Colloid and polymer science, 2012, 290: 1207-1213

 

内部结构不对称磁性复合微球的制备及其影响因素探究,化学学报,2012,70: 345-351.

磁场诱导沉淀聚合制备一维纳米链,中国科学化学2012,42: 1007-1013.


社会兼职 Social Appointments


中国材料研究学会高分子材料与工程分会委员,中国复合材料学会空天动力复合材料及应用专业委员会委员,陕西省化学会常务理事,中国颗粒学会理事,陕西省环境学会理事,《高分子材料》、《化学工程》、《粘接》等国内行业顶尖期刊编委

团队信息 Team Information